\u950c\u9530\u7535\u6c60\u53ef\u4ee5\u5206\u4e3a\u666e\u901a\u950c\u9530\u7535\u6c60\u548c\u78b1\u6027\u950c\u9530\u7535\u6c60\uff0c\u56e0\u4e3a\u5b83\u4eec\u5236\u9020\u7684\u539f\u6750\u6599\u6709\u4e00\u5b9a\u7684\u5dee\u522b\uff0c\u6240\u4ee5\u6027\u80fd\u65b9\u9762\u4e5f\u4f1a\u6709\u6240\u5dee\u522b\uff0c\u90a3\u4e48\u78b1\u6027\u950c\u9530\u7535\u6c60\u4e0e\u666e\u901a\u950c\u9530\u7535\u6c60\u54ea\u4e2a\u597d\u5462\uff1f<\/p>\n\n\n\n
\u78b1\u6027\u950c\u9530\u7535\u6c60\u7684\u6574\u4f53\u6027\u80fd\u8981\u9ad8\u4e8e\u666e\u901a\u950c\u9530\u7535\u6c60\uff1a<\/p>\n\n\n\n
\u78b1\u6027\u7535\u6c60\u7684\u5bb9\u91cf\u660e\u663e\u9ad8\u4e8e\u666e\u901a\u7535\u6c60\uff0c\u7ea6\u662f\u540e\u8005\u76843-8\u500d\uff1b<\/p>\n\n\n\n
\u78b1\u6027\u7535\u6c60\u7684\u653e\u7535\u5bb9\u91cf\u8981\u660e\u663e\u9ad8\u4e8e\u666e\u901a\u7535\u6c60\uff0c\u66f4\u9002\u5408\u5927\u7535\u6d41\u653e\u7535\uff1b<\/p>\n\n\n\n
\u78b1\u6027\u7535\u6c60\u7684\u8d2e\u5b58\u671f\u53ef\u8fbe3-7\u5e74\uff0c\u662f\u666e\u901a\u7535\u6c60\u76843-7\u500d\uff1b<\/p>\n\n\n\n
\u78b1\u6027\u7535\u6c60\u7684\u539f\u6750\u6599\u5229\u7528\u7387\u66f4\u9ad8\uff0c\u5982\u950c\u5229\u7528\u7387\u662f\u666e\u901a\u7535\u6c60\u76843-8\u500d\u3002<\/p>\n\n\n\n
\u6240\u4ee5\u78b1\u6027\u950c\u9530\u7535\u6c60\u6bd4\u666e\u901a\u950c\u9530\u7535\u6c60\u6765\u8bf4\u66f4\u597d\u4e9b\u3002<\/p>\n\n\n\n
\u666e\u901a\u950c\u9530\u7535\u6c60\uff1a\u6b63\u6781\u662f\u77f3\u58a8\u68d2\u548c\u4e8c\u6c27\u5316\u9530\uff08MnO2\uff09\uff0c\u8d1f\u6781\u6750\u6599\u662f\u950c\u7247\uff0c\u7535\u89e3\u8d28\u662f\u6c2f\u5316\u94f5\uff08NH4Cl\uff09\u548c\u6c2f\u5316\u950c\uff08ZnCl2\uff09\u7684\u6dc0\u7c89\u7cca\u72b6\u7269\u3002\u7531\u4e8e\u6b63\u6781\u6709\u77f3\u58a8\u68d2\uff0c\u6240\u4ee5\u666e\u901a\u950c\u9530\u7535\u6c60\u6709\u65f6\u5019\u53c8\u53eb\u4f5c\u78b3\u6027\u7535\u6c60\u3002<\/p>\n\n\n\n
\u78b1\u6027\u950c\u9530\u7535\u6c60\uff1a\u6b63\u6781\u662f\u4e8c\u6c27\u5316\u9530\uff0c\u8d1f\u6781\u662f\u950c\uff0c\u7535\u89e3\u8d28\u4ee5\u6c22\u6c2f\u5316\u94be\uff08KOH\uff09\u8f83\u4e3a\u5e38\u89c1\u3002\u78b1\u6027\u7535\u6c60\u53ef\u4ee5\u8bf4\u662f\u666e\u901a\u950c\u9530\u7535\u6c60\u7684\u5347\u7ea7\u4ea7\u54c1\u3002<\/p>\n\n\n\n
\u78b1\u6027\u950c\u9530\u7535\u6c60\u662f\u4ee5\u950c\u4e3a\u8d1f\u6781\uff0c\u4e8c\u6c27\u5316\u9530\u4e3a\u6b63\u6781\uff0c\u6c22\u6c27\u5316\u94a0\u6216\u6c22\u6c27\u5316\u94be\u4e3a\u7535\u89e3\u8d28\uff0c\u91c7\u53d6\u53cd\u6781\u5f0f\u7ed3\u6784\u5236\u6210\u7684\u7535\u6c60\u3002<\/p>\n\n\n\n
\u4ee5\u950c\u4e3a\u8d1f\u6781\uff0c\u4e8c\u6c27\u5316\u9530\u4e3a\u6b63\u6781\uff0c\u6c22\u6c27\u5316\u94be\u6eb6\u6db2\u4e3a\u7535\u89e3\u6db2\u7684\u539f\u7535\u6c60\u3002\u7b80\u79f0\u78b1\u9530\u7535\u6c60\uff0c\u4fd7\u79f0\u78b1\u6027\u7535\u6c60\u3002\u5176\u4ea7\u54c1\u7cfb\u5217\u90fd\u7528\u5b57\u6bcd\u201cLR\u201d\u8868\u793a\uff0c\u5176\u540e\u7684\u6570\u5b57\u8868\u793a\u7535\u6c60\u7684\u578b\u53f7\u3002<\/p>\n\n\n\n
\u6700\u65e9\u89c1\u8bf8\u4e8e\u5fb7\u56fd\u4e13\u5229\u7684\u78b1\u9530\u7535\u6c60\u662f\u4e00\u79cd\u6e7f\u7535\u6c60\u30021912\u5e74\u53c8\u6709\u4e00\u79cd\u5e72\u7535\u6c60\u53d6\u5f97\u5fb7\u56fd\u4e13\u5229\u3002\u76f4\u52301949\u5e74\u624d\u6709\u7f8e\u56fd\u60a6\u534e\u516c\u53f8\u7684\u201c\u7687\u51a0\u201d\u578b\u7535\u6c60\u6295\u5165\u5e02\u573a\u30021960\u5e74\u5f00\u53d1\u6210\u529f\u5706\u7b52\u5f62\u7ed3\u6784\u4ee5\u540e\uff0c\u78b1\u9530\u7535\u6c60\u624d\u5f97\u4ee5\u8fc5\u901f\u53d1\u5c55\u3002<\/p>\n\n\n\n
\u78b1\u6027\u950c\u9530\u7535\u6c60\u662f\u666e\u901a\u5e72\u7535\u6c60\u7684\u5347\u7ea7\u6362\u4ee3\u7684\u9ad8\u6027\u80fd\u7535\u6c60\u4ea7\u54c1\uff0c\u6709LR6(\u4e94\u53f7)\u548cLR03(\u4e03\u53f7)\u4e24\u79cd\u4ea7\u54c1\u7535\u6c60\u3002\u4ea7\u54c1\u5206\u666e\u901a\u578b(\u542b\u6c5e\u91cf0.60%)\u548c\u5fae\u6c5e\u91cf(\u542b\u6c5e\u91cf\u4e0d\u5927\u4e8e0.025%)\uff0c\u73b0\u6b63\u5728\u5f00\u5c55\u65e0\u6c5e\u578b\u7535\u6c60\u8bd5\u5236\u3002<\/p>\n\n\n\n
\u7535\u6781\u53cd\u5e94\u5f0f<\/p>\n\n\n\n
\u7ebd\u6263\u7535\u6c60\uff1a<\/p>\n\n\n\n
\u8d1f\u6781\u53cd\u5e94\uff1aZn+2OH–2e-=Zn(OH)2<\/p>\n\n\n\n
\u6b63\u6781\u53cd\u5e94\uff1a2MnO2+2H2O+2e-=2MnOOH+2OH-<\/p>\n\n\n\n
\u603b\u53cd\u5e94\uff1aZn+2MnO2+H2O=Zn(OH)2+Mn2O3<\/p>\n\n\n\n
\u4e00\u822c\u7535\u6c60\uff1a<\/p>\n\n\n\n
\u8d1f\u6781\u53cd\u5e94\uff1aZn+2OH-=Zn(OH)2+2e-\uff0cZn(OH)2+2OH-=[Zn(OH)4]2-<\/p>\n\n\n\n
\u6b63\u6781\u53cd\u5e94\uff1aMnO2+H2O+e-=MnOOH+OH-\uff0cMnOOH+H2O+e-=Mn(OH)2+OH-<\/p>\n\n\n\n
\u603b\u53cd\u5e94\uff1aZn+MnO2+2H2O+2OH-=Mn(OH)2+[Zn(OH)4]2-<\/p>\n\n\n\n
(1)\u5706\u7b52\u578b\u7535\u6c60\u7ed3\u6784<\/p>\n\n\n\n
\u78b1\u6027\u950c\u9530\u7535\u6c60\u5177\u6709\u4ee3\u8868\u6027\u7684\u5706\u7b52\u578b\uff0c\u4e0e\u5706\u7b52\u578b\u666e\u901a\u950c\u9530\u7535\u6c60\u7684\u7ed3\u6784\u5e03\u5c40\u6070\u597d\u76f8\u53cd\u3002\u78b1\u6027\u950c\u9530\u7535\u6c60\u4e2d\u5706\u73af\u72b6\u6b63\u6781\u7d27\u6328\u5bb9\u5668\u94a2\u7b52\u5185\u58c1\uff0c\u8d1f\u6781\u4f4d\u4e8e\u6b63\u6781\u4e2d\u95f4\uff0c\u6709\u4e00\u4e2a\u9489\u5b50\u5f62\u7684\u8d1f\u6781\u96c6\u6d41\u5668\uff0c\u8fd9\u4e2a\u9489\u5b50\u88ab\u710a\u5728\u9876\u90e8\u76d6\u5b50\u4e0a\uff0c\u4f5c\u4e3a\u7535\u6c60\u7684\u8d1f\u6781\uff0c\u800c\u94a2\u7b52\u4e3a\u6b63\u6781\u3002\u4e3a\u4e86\u65b9\u4fbf\u5e76\u80fd\u4e0e\u666e\u901a\u950c\u9530\u7535\u6c60\u4e92\u6362\u4f7f\u7528\uff0c\u540c\u65f6\u907f\u514d\u4f7f\u7528\u65f6\u6b63\u8d1f\u6781\u5f04\u9519\uff0c\u7535\u6c60\u5728\u8bbe\u8ba1\u5236\u9020\u65f6\uff0c\u5c06\u4e0a\u8ff0\u78b1\u6027\u950c\u9530\u7535\u6c60\u7684\u534a\u6210\u54c1\u5012\u7f6e\u8fc7\u6765\uff0c\u4f7f\u94a2\u7b52\u5e95\u671d\u4e0a\uff0c\u5f00\u53e3\u671d\u4e0b\uff0c\u518d\u5728\u94a2\u7b52\u5e95\u4e0a\u653e\u4e00\u4e2a\u51f8\u5f62\u76d6(\u5047\u76d6)\uff0c\u6b63\u6781\u4fbf\u4f4d\u4e8e\u4e0a\u65b9\uff1b\u5728\u8d1f\u6781\u5f15\u51fa\u4f53\u4e0a\u710a\u63a5\u4e00\u4e2a\u91d1\u5c5e\u7247(\u5047\u5e95)\uff0c\u8fd9\u6837\uff0c\u5916\u89c2\u4e0a\u78b1\u6027\u950c\u9530\u7535\u6c60\u6b63\u3001\u8d1f\u6781\u6027\u548c\u5f62\u72b6\u4e0e\u666e\u901a\u950c\u9530\u7535\u6c60\u5c31\u4e00\u81f4\u4e86\u3002<\/p>\n\n\n\n
(2)\u5377\u5f0f\u7535\u6c60\u7ed3\u6784<\/p>\n\n\n\n
\u5176\u7ed3\u6784\u4ee5\u91d1\u5c5e\u7f51\u4f5c\u8f7d\u4f53\uff0c\u628a\u6b63\u3001\u8d1f\u6781\u5206\u522b\u538b\u5236\u6210\u8584\u5e26\u72b6\uff0c\u518d\u4e0e\u9694\u819c\u53e0\u5408\u5728\u4e00\u8d77\u5377\u6210\u87ba\u65cb\u72b6(\u7535\u5bb9\u5f0f)\u7ed3\u6784\u7684\u7535\u6c60\uff0c\u8fd9\u79cd\u7ed3\u6784\u7684\u7279\u70b9\u662f\u6b63\u3001\u8d1f\u6781\u4f5c\u7528\u9762\u79ef\u5927\uff0c\u8d85\u7535\u52bf\u5c0f\uff0c\u4ece\u800c\u5728\u4f4e\u6e29\u3001\u5927\u7535\u6d41\u653e\u7535\u65f6\u53ef\u83b7\u5f97\u66f4\u9ad8\u7684\u5bb9\u91cf\u3002<\/p>\n\n\n\n
(3)\u65b9\u578b\u5355\u4f53\u5f0f\u7535\u6c60\u7ed3\u6784<\/p>\n\n\n\n
\u65b9\u578b\u5355\u4f53\u7535\u6c60\u6b63\u3001\u8d1f\u6781\u91c7\u7528\u6781\u7fa4\u5f0f\u7ed3\u6784\uff0c\u6b63\u3001\u8d1f\u6781\u5206\u522b\u538b\u5236\u6210\u65b9\u578b\u8584\u7247\uff0c\u6781\u7247\u4e2d\u95f4\u5939\u6709\u91d1\u5c5e\u96c6\u6d41\u7f51\u3002<\/p>\n\n\n\n
\u5236\u4f5c\u65b9\u6cd5<\/p>\n\n\n\n
\u6700\u666e\u53ca\u7684\u78b1\u9530\u7535\u6c60\u6709\u5706\u7b52\u5f62\u548c\u7ebd\u6263\u5f62\u4e24\u79cd,\u6b64\u5916\u8fd8\u6709\u65b9\u5f62\u548c\u6241\u5f62\u7b49\u54c1\u79cd\u3002\u5706\u7b52\u7ed3\u6784\u7535\u6c60\uff08\u89c1\u56fe\uff09\u7684\u5916\u58f3\u4e3a\u4e00\u5e26\u6709\u6b63\u6781\u5e3d\u7684\u9540\u954d\u94a2\u58f3\uff0c\u5b83\u517c\u4f5c\u6b63\u6781\u96c6\u7535\u4f53\u3002\u58f3\u5185\u4e0e\u4e4b\u7d27\u5bc6\u63a5\u89e6\u7684\u662f\u7528\u7535\u89e3\u4e8c\u6c27\u5316\u731b\u3001\u77f3\u58a8\u548c\u78b3\u9ed1\u538b\u5236\u6210\u7684\u6b63\u6781\u73af\uff08\u9634\u6781\uff09\u3002\u4e2d\u95f4\u586b\u5145\u7531\u950c\u7c89\u548c\u51dd\u80f6\u78b1\u6db2\u8c03\u5236\u6210\u7684\u950c\u818f,\u5373\u8d1f\u6781\u80f6\uff08\u9633\u6781\uff09,\u5176\u5185\u63d2\u6709\u4e00\u6839\u9ec4\u94dc\u96c6\u7535\u4f53\u3002\u6b63\u8d1f\u6781\u4e4b\u95f4\u7528\u8010\u78b1\u5438\u6db2\u7684\u9694\u79bb\u7ba1\u9694\u79bb\u3002\u8d1f\u6781\u96c6\u7535\u4f53\u4e0e\u8d1f\u6781\u5e3d\u76f8\u710a\u63a5\uff0c\u5e76\u5957\u5165\u5851\u6599\u5c01\u5708\u3002\u5c06\u6b64\u7ec4\u5408\u4ef6\u63d2\u5165\u94a2\u58f3\u5e76\u5377\u8fb9\u5bc6\u5c01\uff0c\u94a2\u58f3\u5916\u7528\u70ed\u7f29\u6027\u8584\u819c\u5546\u6807\u5305\u4f4f\uff0c\u5373\u6210\u4e3a\u5546\u54c1\u7535\u6c60\u3002\u7ebd\u6263\u5f0f\u78b1\u9530\u7535\u6c60\u7684\u7ed3\u6784\u548c\u5c3a\u5bf8\u89c4\u683c\u57fa\u672c\u4e0a\u4e0e\u950c\u94f6\u6263\u5f0f\u7535\u6c60\u76f8\u540c\u3002\u7535\u6c60\u5185\u6d3b\u6027\u7269\u8d28\u7684\u5178\u578b\u914d\u65b9\uff08\u8d28\u91cf\uff09\uff1a\u6b63\u6781\u4e3a\u7535\u89e3\u4e8c\u6c27\u5316\u953090\uff5e92%\uff0c\u77f3\u58a8\u7c898\uff5e9%\uff0c\u4e59\u7094\u70ad\u9ed10.5\uff5e1%\uff1b\u8d1f\u6781\u4e3a\u6c5e\u9f50\u950c\u7c8988\uff5e90%\uff0c\u6c27\u5316\u950c5\uff5e7%\uff0cCMC\u94a0\u76d03\uff5e4%\uff0cKOH\u6eb6\u6db2\uff08\u5916\u52a0\uff09\u9002\u91cf\u3002\u7535\u89e3\u6db2\u4e3a8\uff5e12NKOH\u6eb6\u6db2\uff0c\u5176\u4e2d\u6eb6\u5165\u9002\u91cf\u6c27\u5316\u950c\u3002<\/p>\n\n\n\n
\u6027\u80fd\u7279\u5f81<\/p>\n\n\n\n
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